No, Human Medications were not meant for pet use. You are more likely to only succeed in damaging your dogs health. As the others have mentioned there is a mis-mate injection, but you only have a 24 hour window to do so. Also when a dog mate it prolongs the heat cycle, so you're best bet is to get her spayed or you will likely be dealing with more "accidents" and/or unwanted litters. This means instead of saving money by cheaping out on the procedure it will in fact cost you a whole lot more, in vet visits to get the shots or in the costs of taking care of the puppies, not to mention if something goes wrong in pregnancy or delivery and your dog has to be rushed in. This doesn't just hurt you and your dog, this hurts every dog in every shelter in the world. Please do the right thing and get her spayed.
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