OK. I suspected something like that.
I looked at
Crystal structure - Wikipedia, the free encyclopedia
it looks like you need c and a from the picture there unless we're assuming that a=c. The picture says a!=c but I assume they mean that a does not have to equal c. I'll go with that until the OP tells me otherwise.
Volume of a hexagonal prism is area of base * height. Height = c. base is hexagon and area of regular hexagon is

. Therefore since we're assuming that a=c the volume is

but that = 2.598c^3 which is not what the OP wrote. I guess we'll have to wait for him to supply more info and also tell us if he need to include proof of the area of a hexagon.