Any time you have sex, especially unprotected sex, pregnancy is possible. So yes, you could be pregnant.
The yellow discharge is a concern. Yellow is not a normal color for vaginal discharge. But, the discharge would have nothing to do with pregnancy.
Wait until your next period. If you miss it wait a week or two, then take a pregnancy test using first morning urine. If it's negative then wait until your next period is due, and test again if you miss it, or see a doctor for a more accurate blood test.
As for the discharge, I would see a doctor about that.
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