What's the age difference between you, your brother, and his lady friend?
Do you and your brother get along; ask him what he thinks of the situation?
I can only assume the time when you get to hang out with her is when he brings her over to the house so just turn up the charm and start having conversations with her and your brother. This may be harsh but as the conversation goes on try to weed your brother out of it. I'm not saying stand in between the two, that would be rude.
But before making a move on her I suggest talking to your brother first, and through him you just find out information about her that can be beneficial.
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