Hmm... I have a cat that wasn't too happy about it when I first started brushing him. He's short-haired and doesn't even shed much, but for some reason pukes it up easily so I brush him anyway. He would try to bite me.
Most cats love brushing so I thought that weird. (The other cat just loves it, everywhere, even her belly, and rolls around all over, content as can be.) I once tried sneaking up behind him and running the brush down his back when he didn't see it coming, and he actually purred. I kind of started wondering if he just didn't trust it or something, thought it was something trying to attack him, and just bit and moved away before bothering to find out.
I just kept that up, trying to sneak a few brushes in before he would look and see what I had. Slowly over time he got used to it and now sometimes even stays still and likes it. Sometimes he still gets upset and runs off.
EDIT: Forgot to mention that you can try spraying Feliway around her or Rescue Remedy. Just Google them and you'll find them easily enough.
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