format the partition of the xp you do not want, I would recommend keeping the one that is on C: drive
After drive is formatted you need to edit the boot.ini file so that you will no longer have the option menu when you start PC to choose which OS to boot to
On c: drive, you need to edit boot.ini 
right click on boot.ini and choose edit 
it will look similar to this 
 
	
		
			
			
				[boot loader] 
timeout=30 
default=multi(0)disk(0)rdisk(0)partition(1)\WINDOW  S 
[operating systems] 
multi(0)disk(0)rdisk(0)partition(1)\WINDOWS=”Micro  soft Windows XP Professional” /fastdetect /NoExecute=OptIn 
multi(0)disk(0)rdisk(0)partition(1)\WINDOWS=”Micro  soft Windows XP Professional” /fastdetect /NoExecute=OptIn
			
		
 
	 
 
You need to remove the line that reflects the version you removed to make it look like this 
 
	
		
			
			
				[boot loader] 
timeout=30 
default=multi(0)disk(0)rdisk(0)partition(1)\WINDOW  S 
[operating systems] 
multi(0)disk(0)rdisk(0)partition(1)\WINDOWS=”Micro  soft Windows XP Professional” /fastdetect /NoExecute=OptIn
			
		
 
	 
 So you will only have 1 line that is like the last line, not 2 as i first pic
now you will just boot into xp so that you could install NT to the formatted partition