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-   -   Titration (https://www.askmehelpdesk.com/showthread.php?t=415664)

  • Nov 13, 2009, 10:48 AM
    nojha1
    Titration
    A 10.00 mL sample of the water from the holding tank requires 35.47 mL of 8.193 x 10-4 M EDTA to reach the end point. (A) Based on this titration, what is the concentration of lead(II) ions in the holding tank?

    here,
    I try to start the problem by writing following equation:
    Pb2+(aq) + EDTA2-(aq) <-> PbEDTA(aq)
    but I have no idea what to do next... help!
  • Nov 13, 2009, 11:24 AM
    Perito
    Quote:

    Originally Posted by nojha1 View Post
    A 10.00 mL sample of the water from the holding tank requires 35.47 mL of 8.193 x 10-4 M EDTA to reach the end point. (A) Based on this titration, what is the concentration of lead(II) ions in the holding tank?

    here,
    I try to start the problem by writing following equation:
    Pb2+(aq) + EDTA2-(aq) <-> PbEDTA(aq)



    With this equation, you know that one mole of EDTA reacts with one mole of Pb(2+). You were told that the titration has an "end point". This implies that the amount of EDTA used was exactly the amount required to react with the Pb(2+) -- no more, no less.

    1. You know that you had a 10 mL sample containing Pb(2+) and you're trying to determine how much lead is in it. The volume is so that you can figure out a concentration after you determine the amount of lead in the sample.

    2. The EDTA concentration is given as

    The units (moles/liter) or M (molar) is important.

    3. You used 35.47 mL (0.03547 Liters) of solution.

    First, calculate the number of moles of EDTA you used:



    Note how the "Liters" cancels -- just like arithmetic. Since one mole of EDTA reacts with one mole of Pb(2+), this is also the number of moles of Pb in 10.0 mL of the sample.

    Concentration is expressed in moles/liter. Can you now figure out the concentration of lead in the sample?
  • Nov 14, 2009, 10:05 AM
    nojha1
    Quote:

    Originally Posted by Perito View Post


    With this equation, you know that one mole of EDTA reacts with one mole of Pb(2+). You were told that the titration has an "end point". This implies that the amount of EDTA used was exactly the amount required to react with the Pb(2+) -- no more, no less.

    1. You know that you had a 10 mL sample containing Pb(2+) and you're trying to determine how much lead is in it. The volume is so that you can figure out a concentration after you determine the amount of lead in the sample.

    2. The EDTA concentration is given as

    The units (moles/liter) or M (molar) is important.

    3. You used 35.47 mL (0.03547 Liters) of solution.

    First, calculate the number of moles of EDTA you used:



    Note how the "Liters" cancels -- just like arithmetic. Since one mole of EDTA reacts with one mole of Pb(2+), this is also the number of moles of Pb in 10.0 mL of the sample.

    Concentration is expressed in moles/liter. Can you now figure out the concentration of lead in the sample?

    Thank You,!

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