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-   -   Hess's Law (simple) (https://www.askmehelpdesk.com/showthread.php?t=343721)

  • Apr 20, 2009, 05:58 AM
    lorijessica16
    Hess's Law (simple)
    1) NaOH(s)--> Na+(aq) + OH- (aq)
    2) Na+(aq) + OH(aq) + H+(aq) + Cl-(aq) --> H2O + Na+(aq) + Cl-(aq)

    Target
    equation: NaOH(s) + H+(aq) + Cl(aq)--> H20 + Na+(aq) + Cl-(aq)

    I need help solving this.. Thanks
  • Apr 20, 2009, 06:05 AM
    Perito
    Quote:

    Originally Posted by lorijessica16 View Post

    1) NaOH(s)--> Na+(aq) + OH- (aq)
    2) Na+(aq) + OH(aq) + H+(aq) + Cl-(aq) --> H2O + Na+(aq) + Cl-(aq)

    Target
    equation: NaOH(s) + H+(aq) + Cl-(aq)--> H20 + Na+(aq) + Cl-(aq)

    Actually, it appears you have solved it.







    therefore, adding them together and eliminating redundancies on both sides of the "-->",



    Depending on how you wish to express it, you can write it this way:



    In this case, you don't emphasize that the NaCl is dissociated. If you wish to emphasize that NaOH and HCl are dissociated you can write this:



    But the Na+ and Cl- on both sides of the equation is sort of silly. They're simply "spectator ions".




    I'm not sure how this relates to Hess's law which is about energy changes.

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