What is the best paint 100 Percent Acrylic Dunn Edwards or Frazee?

It's not quite that easy. Each brand of paint has good lines and awful lines. See here as an example of what I mean.

The other problem is that paint brands are like car brands. If we complare "top of the line", as in Mercedes vs. BMW, you'll find varying opinions.

Frankly, I've never heard of either brand, so I'll guess that they are regional. I'd ask high end painting contractors in your area which one they think is best... or if they think even another brand is better.

Good luck with the project!