My sister has a 1986 cutlass ciera oldsmobile 4 cyl. It started pinging rather loudly yesterday . It only does it on excelleration. She has been using cheap gas that is 10% ethanol. Today we filled the tank with 93 ocatane EXXon and put in a bottle of Champion fuel system cleaner. Will this help? If so how long might it take? Also what about the EGR valve could that be the problem?