Looking for a Humane DIY Home Remedy to have some unwanted Chipmunks Relocate...

Best way is trapping them and taking them far enough away that they won't come back. (Joke) For instance, the co-worker that you hate that lives across town's garden.(joke)

Here's a good site with a variety of traps from homemade to purchased:

Chipmunk Trapping Methods and Bait

Just get some live traps, Harbor Freight has them fairly cheap! Catch them and release them 5 miles from where you caught them.