You need to work 'backwards'.
1. Find the number of moles of hydrogen peroxide used to react with Ce^2+.
Number of moles = Concentration of H2O2 x Volume of H2O2
Be careful about the units!
2. Find the number of moles of Ce^2+ present in your conical flask, using the mole ratio given in your equation.
3. Find the number of moles of H2O2 in your initial 500 mL solution.
4. Hence, find the number of moles of Ce^2+ present in the 50 mL sample.
5. Calculate the concentration of Ce^2+ using 4, in mol/L
6. Find this concentration in g/L.
Post what you get! :)
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