Ask Experts Questions for FREE Help !
Ask
    lisanoce's Avatar
    lisanoce Posts: 30, Reputation: 1
    Junior Member
     
    #1

    Apr 26, 2009, 08:29 AM
    stoichiometry of redox reactions
    How many grams of magnesium are needed to displace all the silver from 25.0 g of silver nitrate?

    I think that your supposed to write the redox equation first but I need help writing it out. Also do you have to use the 25.0 g of silver in order to get the grams of magnesium? Thanks
    Perito's Avatar
    Perito Posts: 3,139, Reputation: 150
    Ultra Member
     
    #2

    Apr 26, 2009, 09:32 AM

    These are the half reactions. From these you can get the balanced equation.





    Yes, you do need to use the 25.0 g of Ag in order to figure out the grams of magnesium. 1. From the mass of Ag, you determine the number of moles of Ag. w. Knowing the number of moles of Ag and the stoichiometry, you figure out the number of moles of Mg that are required. 3. From the number of moles of Mg you figure out the mass of Mg.
    lisanoce's Avatar
    lisanoce Posts: 30, Reputation: 1
    Junior Member
     
    #3

    Apr 26, 2009, 12:01 PM
    Quote Originally Posted by Perito View Post
    These are the half reactions. From these you can get the balanced equation.





    Yes, you do need to use the 25.0 g of Ag in order to figure out the grams of magnesium. 1. From the mass of Ag, you determine the number of moles of Ag. w. Knowing the number of moles of Ag and the stoichiometry, you figure out the number of moles of Mg that are required. 3. From the number of moles of Mg you figure out the mass of Mg.

    Is this right?

    Mg --> Mg^2+ + 2e-
    2(Ag+ + e- --> Ag)
    ---------------------------
    Mg + 2Ag+ + 2e- ---> Mg2+ + 2e- + 2Ag
    Mg + 2Ag+ --> Mg2+ + 2Ag


    25.0g x
    ------ = --------------
    107.9g x 2mol 24.3 g x 1 mol


    x = 2.82g of Mg ( I'm not sure if i made a mistake )

    Oh and I don't get why you didn't use AgNO3 in the half reactions.
    lisanoce's Avatar
    lisanoce Posts: 30, Reputation: 1
    Junior Member
     
    #4

    Apr 26, 2009, 12:03 PM
    Quote Originally Posted by lisanoce View Post
    Is this right?

    Mg --> Mg^2+ + 2e-
    2(Ag+ + e- --> Ag)
    ---------------------------
    Mg + 2Ag+ + 2e- ---> Mg2+ + 2e- + 2Ag
    Mg + 2Ag+ --> Mg2+ + 2Ag


    25.0g x
    ------ = --------------
    107.9g x 2mol 24.3 g x 1 mol


    x = 2.82g of Mg ( im not sure if i made a mistake )

    Oh and I don't get why you didnt use AgNO3 in the half reactions.


    25.0g x
    ------ = --------------
    107.9gx2mol 24.3g x 1 mol


    x = 2.82g of Mg
    lisanoce's Avatar
    lisanoce Posts: 30, Reputation: 1
    Junior Member
     
    #5

    Apr 26, 2009, 12:06 PM
    Quote Originally Posted by lisanoce View Post
    25.0g x
    ------ = --------------
    107.9gx2mol 24.3g x 1 mol


    x = 2.82g of Mg

    Ugh this is my first time using this sorry it keeps coming out wrong : S


    25.0g/107.9g(2 mol) = x/24.3g(1 mol)

    x= 2.82 g of Mg
    Perito's Avatar
    Perito Posts: 3,139, Reputation: 150
    Ultra Member
     
    #6

    Apr 26, 2009, 12:18 PM

    Your equation is correct



    The rest of it is almost correct. You have 25 g of Ag(NO3). I probably misled you by mentioning only silver instead of silver nitrate. The problem specified 25 g of silver nitrate, so you need to use the molecular weight of silver nitrate, 169.87 g/mole.


    1
    According to the equation, you need 1 mole of Mg for every 2 moles of Ag+ so


    169.87

    The atomic weight of Mg is 24.3050 so you need



    The reason I didn't use Ag(NO3) in the half reactions, but only used Ag+ is that the NO3- group, in this case, doesn't do anything. It's merely a "spectator ion". You could have written



    and this would also have been correct.

    in one equation, like you had, the math becomes



    unless I made a mistake.
    lorijessica16's Avatar
    lorijessica16 Posts: 9, Reputation: 1
    New Member
     
    #7

    Apr 26, 2009, 12:28 PM
    Quote Originally Posted by lisanoce View Post
    How many grams of magnesium are needed to displace all the silver from 25.0 g of silver nitrate?

    I think that your supposed to write the redox equation first but i need help writing it out. Also do you have to use the 25.0 g of silver in order to get the grams of magnesium? thanks

    Ohh I get it now thanks!
    Perito's Avatar
    Perito Posts: 3,139, Reputation: 150
    Ultra Member
     
    #8

    Apr 26, 2009, 12:36 PM

    Hang in there. It's fun once you learn it.

Not your question? Ask your question View similar questions

 

Question Tools Search this Question
Search this Question:

Advanced Search


Check out some similar questions!

Stoichiometry of redox reactions [ 3 Answers ]

I just need someone to check my work. The question was: Solder is an alloy containing the metals tin and lead. A particular sample of this alloy weighing 1.50 g was dissolved in acid. All the tin was converted to the +2 oxidation state. Next, it was found that 0.368 g of Na2Cr2O7 was required to...

Redox and Stoichiometry Anyone? [ 1 Answers ]

I am studying chemistry and I am HORRIBLE! I simply do not understand redox and what is up with stoichiometry? Can someone explain both these "topics" to me? Thank you much. The Dispersion

Redox reactions [ 1 Answers ]

What is the chemical reaction between potassium hydroxide and potassium permagnate

Redox Titrations [ 1 Answers ]

I need help with this question on redox titrations. It says that a 10.00mL sample of an aqueous solution of hyrdrogen peroxide, H_2O_2(aq) is treated with an excess of KI(aq). The liberated I_2 requires 28.92 mL of 0.1522 M Na_2S_2O_3 for its titration. Is the H_2O_2(aq) up to its full strength (3%...


View more questions Search