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1.  Figure out the molecular weight (formula weight) of NaOH.  You have 4 grams of NaOH.  The molecular weight is in grams/mole so if you divide grams by grams/mole, you'll end up with moles.  It's approximate because NaOH absorbs water and CO2 from the air and the weight is approximate -- not accurate. 
 
2.  From #1, you know the approximate number of moles.  Benzoic acid has only one hydrogen ion to react with the NaOH, so 1 mole reacts with 1 mole (I'll let you write down the equation and balance it).  You have the number of moles from #1 so divide that by the 200 mL of solution to get moles/mL.  Since you now know the number of moles you'll need, divide that by moles/mL to get mL.
     
     
    
    
    
    
    
    
  
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