Here is a useful link
http://www.epa.gov/iaq/pubs/ozonegen.html
We used ozone in a business I worked at. I'm a chemist who formulated inks for the flexible packaging industry. Its used to treat plastics and films before printing, increasing the surface tension of the plastic, which helps with proper printing... getting the ink to lay down correctly.
So we used a wand, much like the electric hand mixer wands you can use to make drinks, crush ice, only this had an electrical disharge unit on the bottom. You could actually see little purple arcs jumping from the wand to the plastic substrate. Big, stationary units are also used press-side, charging films rapidly as the are prepared to print. Point is, we were around it, could smell it, inhaled it. But my opinion is its like being a coal miner... you know its not good for you to breathe that air in. luckily I'm no longer in the business. I expect its just seen as a workplace hazard, like working with gasoline or toluene...
Anyway, while I like the smell of ozone in small amounts, I just have a hard time believing that the ionizers that are sold 1) do a good job at low levels and/or 2) are safe at higher levels of ozone.
The website I linked confirms that there are clear problems with this technology... you're hoping to find this fine line between being useful and being dangerous. I'm not sure that place exists.