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    rockerchick26's Avatar
    rockerchick26 Posts: 93, Reputation: 22
    Junior Member
     
    #1

    Nov 29, 2009, 03:13 PM
    Thermodynamics/Calorimetry Practice Problems
    I was wondering if someone might be able to check my answers to some thermo questions:

    1. A 625 mL sample of water was cooled from 50 C to 10 C. How much heat was lost?
    My Answer: -104500 J


    2. How many joules are required to change the temperature of 60g of water from 23.3 C to 38.3 C?
    My Answer: 3887.4 J


    3. Calculate the final temperature when 50 mL of water at 60 C are added to 25 mL of water at 20 C.
    My Answer: 46.7 C


    4. A piece of metal weighing 5.10 g at a temperature of 48.6 C was placed in a calorimeter containing 20.00 mL of water at 22.1C, and the final equilibrium temperature was found to be 28.2 C. What is the specific heat of the metal?
    My Answer: 4.9J/g*C


    5. If the specific heat of methanol is 2.51 J/K*g, how many joules are necessary to raise the temperature of 250 g of methanol from 18 C to 33 C?
    My Answer: 9412.5 J


    6. When a 3.25g sample of solid sodium hydroxide was dissolved in a calorimeter in 100.0 g of water, the temperature rose from 23.9 C to 32.0 C. Calculate deltaH (in kJ/mol NaOH) for the solution process:

    NaOH (s) ----> Na+(aq) + OH (aq)

    Assume it's a perfect calorimeter and that the specific heat of the solution is the same as that of pure water.

    My Answer: -3495.84 J

    :D
    Thanks for your help!
    Unknown008's Avatar
    Unknown008 Posts: 8,076, Reputation: 723
    Uber Member
     
    #2

    Dec 1, 2009, 06:45 AM

    1. If you take the specific heat capacity of water to be 4.18, then yes. I assume you take it as 4.18 everywhere else.

    2. Now, you are taking the specific heat capacity of water as 4.32? :confused: If you take 4.18, then it's not right.

    3. Yes. Correct.

    4. Yes.

    5. Correct.

    6. Nope.
    ---------------
    I'l show you the 6th one.
    1st basic mistake, you have to answer in kJ/mol and not in J.
    2nd, you must have been lost in your calculations.

    1. Evaluate the heat absorbed by the water.



    2. Now, 3.25 g of NaOH is 0.0825 mol of NaOH (Mr = 40; moles = 3.25/40)

    That 0.0825 mol gives off 3385.8 J
    Therefore, 1 mole gives off 41041 J (3385.8/0.0825)

    That means that

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