View Full Version : Alkene and Alkane problem
lemon14
Nov 17, 2010, 11:15 AM
After the hydrogenation of 22.4 L of an alkene A results 3 g of alkane B. How to find the alkene?
Unknown008
Nov 17, 2010, 12:06 PM
Is this the whole problem? I'm not sure I understand...
Okay, it seems that you have 1 mol of an alkene at stp (22.4 L is one mole of gas at stp)
When you hydrogenate this, you get 3 g of alkane?
That's very little... it's less than a mole of carbon while we had exactly one at the start... =/
lemon14
Nov 18, 2010, 06:40 AM
Yes, this is the whole problem. I know that it doesn't give much information, but I thought I was missing something.
At first I thought about writing the reaction:
C_n H_2n + H_2 \rightarrow C_n H_{2n+2} but from now on I don't know what to do.
Thank you, anyway! :)
Unknown008
Nov 18, 2010, 06:56 AM
You are sure there is nothing more mentioned, no conditions to be assumed (like pressure, temperature)?
And just in case, I misunderstand, is the 22.4 L the volume of alkene or the volume of hydrogen gas?
lemon14
Nov 19, 2010, 06:19 AM
22.4 L is the volume of alkene and the reaction is in stp.
Unknown008
Nov 19, 2010, 06:30 AM
Okay... this will mean you have an initial number of moles of alkene of 1.
This will yield 1 mole of alkane, or is there a specific yield involved?
Because 3 g is really small... even 1 mol of alkene doesn't have such a mass.
lemon14
Nov 19, 2010, 07:00 AM
No, there isn't a specific yield of alkane involved, only those 3 g.
Maybe the problem is mistaken. Don't bother about it anymore. I'll post the solution if I succeed in find it.
Unknown008
Nov 19, 2010, 07:11 AM
Okay, because this question really seems to have something wrong. I'll be waiting :)
lemon14
Dec 5, 2010, 11:50 AM
C_nH_{2n} + H_2 \rightarrow C_nH_{2n+2}
C_nHN{2n} = 12n+2n=14n
C_nH_{2n+2} = 12n + 2n +2=14n+2
14n...................22.4 L
x.......................2.24 L (there is mistake in the problem)
x=1.4 n
1.4n(14n+2)=14n*3
19.6n + 2.8 = 42
n=\frac{42-2.8}{19.6}=2
the forumula is: C_2H_4
Unknown008
Dec 5, 2010, 12:03 PM
Well, that was the problem, there were initially 0.1 mol of A, reacting with excess H2 gas to form 3 g of alkane.