I assume you are resident. Check box (e)
Her passport is sufficient. I am confident you do not wish to commit perjury when you sign.
You fill out your tax return as filing jointly and submit that together with the W-7 to:
Internal Revenue Service
ITIN Operation
P.O. Box 149342
Austin, TX 78714-9342
Your wife will elect to be treated as a US resident under sec 6013(h). Thus, you must report her income from India. But, she is entitled to exclude her income and accordingly, may file a Form 2555 or 2555EZ to exclude her income from India.
The election may take this form:
1.We declare that one spouse was a non-resident alien, and the other spouse a U.S. citizen, or resident on the last day of the tax year 2008 , and we choose to be treated as U.S. residents for the entire year and;
2. Our names, addresses, and social security/ taxpayer identification numbers are as follows:
The fact that your wife does not yet have a number will be handled by the ITIN operation.
You would be well served if you locate a certifying acceptance agent in your area. See;
Acceptance Agent Program