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Of course this could turn into a different discussion altogether. If you truly believe that your god listens to prayer and is all powerful, all knowing then you would be justified in praying and letting god answer your prayers to save that soul. Otherwise you are saying that praying or an all-seeing all-powerful god may not be 100% correct ie. doubt.
No, I meant that while getting medical help, I would pray as well. I wouldn't call it doubt but just being human and we depend on eachother to survive.