I don't know of any one specific site that will give you all of that info for free. Best to go by application. Do a Google search that includes the following: [Office application] + tutorial + free
For example: Excel 2003 + tutorial + free gives
this result.
As well there are many excellent books available that you can purchase inexpensively, here one as an example:
http://www.amazon.com/How-Everything...e=UTF8&s=books