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If you truly want to be someone's friend, you will keep phone time to a minimum until AFTER you have developed a connection with them. After that time, conversation is easy, including on the phone.
Be there in person until then.
As for phone etiquette, girls like to talk and express their feelings. You can easily spark a conversation by telling her something you liked/disliked about your day, what you did...then ask her what she thinks about it. Ask about her day, friends, classes, teachers, pet peeves.
Be sure to listen. Everything she says will make you think about how you feel about the same issues. Tell her.
Don't talk too long. Hanging up while you two are still doing well is a good rule. "I have to go in a minute, so what was that last thing you were saying before I go?"
It's not so much a trick to talking on the phone, it's about actually caring about the person you're talking to. If you care, the questions are real.