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    darmabiala's Avatar
    darmabiala Posts: 2, Reputation: 1
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    #1

    Nov 24, 2009, 10:33 PM
    How to calculate the molar heat of a solution and a heat of a solution
    The calorimeter is prepared with 44.96 g of water, both at 22.6 Celsius. 2.42 g of salt are

    dissolved in the water ( note the total solution mass) and the temperature falls to 19.9

    Celsius . Calculate the heat of the solution for the salt. If the salt is potassium chloride,

    calculate the molar heat of solution.

    1. Finding the heat of solution for the salt:

    water:
    m = 44.96 g
    T initial= 22.6 Celsius
    T final= 19.9 Celsius

    Salt:
    m= 2.42 g
    T initial= 22.6
    T final= 19.9 Celsius

    delta T = 2.7 Celsius
    C = 4.184 J/ g Celsius

    delta Q = mC delta T
    = (44.96 g) ( 4.184 J/g celcius) ( 2.7 celcius)
    = 507. 90 J

    2. Finding the molar heat of the solution: ( really not sure about this)

    m = 44.96 g
    MW = 74.55 g/mol

    mol = m/MW
    = 44.96 g / 74.55 g/mol
    = 0.603 mol

    Molar heat: heat/mol
    507. 90 J /0.603 mol
    = 842.3 J/mol
    =842.3 x 10 -3 KJ/mol
    Unknown008's Avatar
    Unknown008 Posts: 8,076, Reputation: 723
    Uber Member
     
    #2

    Nov 25, 2009, 10:25 AM

    For the second part:

    You're right to be not sure.

    You have found that 2.42 g of KCl absorb 507.9 J.
    How many moles if 2.42 g of KCl? Because you have to find the energy absorbed by 1 mole of KCl.

    So, using the MW, 2.42 g is 0.0325 mol
    Therefore, 0.0325 mol of KCl absorb 507.9 J.

    How much heat is absorbed by 1 mol of KCl?

    I hope it helped! :)
    darmabiala's Avatar
    darmabiala Posts: 2, Reputation: 1
    New Member
     
    #3

    Nov 25, 2009, 10:50 PM
    Yes, it did help thank you so much

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